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Atacamite

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Atacamite
Atacamite from Mt. Gunson mines, South Australia
General
CategoryHalide mineral
FormulaCu2Cl(OH)3
IMA symbolAta[1]
Strunz classification3.DA.10a
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnma
Unit cella = 6.03, b = 9.12
c = 6.865 [Å]; Z = 4
Identification
ColorBright green, dark emerald-green to blackish green
Crystal habitSlender prismatic crystals, fibrous, granular to compact, massive
TwinningContact and penetration with complex twinned groupings
CleavagePerfect on {010}, fair on {101}
FractureConchoidal
TenacityBrittle
Mohs scale hardness3–3.5
LusterAdamantine to vitreous
StreakApple green
DiaphaneityTransparent to translucent
Specific gravity3.745–3.776
Optical propertiesBiaxial (−)
Refractive indexnα = 1.831 nβ = 1.861 nγ = 1.880
Birefringenceδ = 0.049
PleochroismX = pale green; Y = yellow-green; Z = grass-green
2V angleCalculated: 74°
Dispersionr < v, strong
References[2][3][4][5]

Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1802 by Dmitri de Gallitzin.[2] The Atacama Desert is also the namesake of the mineral.

Occurrence

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Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite.[2] Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported as a volcanic sublimate from fumarole deposits, as sulfide alteration products in black smokers.[3] The mineral has also been found naturally on oxidized copper deposits in Chile, China, Russia, Czech Republic, Arizona, and Australia.[6] It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs.[3]

Synthetic Occurrence

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Atacamite has been discovered in the patina of the Statue of Liberty, and as alteration of ancient bronze and copper artifacts. The bronze of the Antikythera mechanism had turned to atacamite under the sea.[7]

The mineral has been found as a pigment in sculpture, manuscripts, maps, and frescoes discovered in Eurasia, Russia, and Persia.[6]

Biomineral

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Atacamite occurs as a biomineral in the jaws of bloodworms.[8][9]

References

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  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Atacamite on Mindat.org
  3. ^ a b c Handbook of Mineralogy
  4. ^ Atacamite on Webmineral
  5. ^ Mineralienatlas
  6. ^ a b "Atacamite – CAMEO". cameo.mfa.org. Retrieved 2017-10-15.
  7. ^ Alex Wilkins (Apr 17, 2025). "Ancient computer's gears may not have been able to turn". New Scientist.
  8. ^ Lichtenegger HC, Schöberl T, Bartl MH, Waite H, Stucky GD (October 2002). "High abrasion resistance with sparse mineralization: copper biomineral in worm jaws". Science. 298 (5592): 389–92. Bibcode:2002Sci...298..389L. doi:10.1126/science.1075433. PMID 12376695. S2CID 14001250.
  9. ^ Lichtenegger HC, Schöberl T, Ruokolainen JT, et al. (August 2003). "Zinc and mechanical prowess in the jaws of Nereis, a marine worm". Proc. Natl. Acad. Sci. U.S.A. 100 (16): 9144–9. Bibcode:2003PNAS..100.9144L. doi:10.1073/pnas.1632658100. PMC 170886. PMID 12886017.
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